Oil Oxidation & Varnish Defined

DF Sales&Marketing

Oil Tech Moderator
As oil ages, it degrades through oxidation and thermal decomposition. The additives, which are performance-enhancing chemicals, are consumed during the life of the fluid. The decomposition by-products of aging increase over the life of the oil forming varnish.

Because varnish is polar, it is attracted to metal surfaces. It starts as a sticky, soft residue and attracts wear debris, forming a sandpaper-like surface. In time, it ends up as a tenacious, hard lacquer.

Oil that has oxidized generally does not lubricate well. It can reduce oil flow, plug filters, cause valves to stick, increase friction, inhibit heat transfer and elevate operating temperature. Because varnish acts as an insulator, cooling capacity can be diminished. In addition, oxidation shortens component life, affecting valves, filters, pumps, bearings and seals. The result is diminished performance.

Keep these things in mind when choosing the oil you will be using as well as performing scheduled maintenance.

......just thought you should know!

Dick
 
Hi dick,
you have touched on one subject I hold in high importants.
I am sensitive to this due to an aircraft background where the air cooled engines are exposed to very high oil and top end temperatures. Piston, valve and turbo charger failure is a real problem under normal usage and of course misuse.

While oxidation seldom comes into play in drag racing it does in high performance and heavy duty car and truck applications.

I drive a late model turbo diesel truck and broke it in on mineral based oil some 8k miles worth. I just switched over to the synthetic version. I have always run synth. Oils in my vehicles that I use as my dd. Do you think it is wise and beneficial in this circumstance? Turbo and, piston/ring temperatures can exceed petroleum oil coaking limits.

Correct me if I am wrong here but synthetic base stocks offer a greater resistance to oxidation and coaking under high temperature usage. A naturally stable viscosity requires smaller amounts of viscosity stabilizers if they require any at all.

I guess what I am ultimately trying to get at is this. Do synthetics give an engine the benefits I wrote of? I realize that not all engine regimes will benefit from synthetics but under certain circumstances is the added cost really add to engine protection?

Thanks for your input.
Robert
 
Hi Robert,

I've read quite a few of the posts and comments you have made in the forum section, and have a great respect for your knowledge which you have shown on the various topics. I'm flattered that you have given me the chance to express my opinions about the subject of "synthetic vs mineral" engine oil.

First off, in aircraft (piston type engines) use, all engine oils which contain zinc in any level are taboo.....the reason being that it effects the silver wrist pins in those engines, and you sure don't want to have a seized piston while up in the air. The aircraft engine oil business has been pretty much sewed up by shell with their "aero-shell" product line. To even think about bringing in an oil for piston aircraft engines would be astronomically staggering price wise, as the oil would have to be approved by engine for each engine out there, of which there are literally thousands, and the cost involved with the various testing procedures and of course the faa could easily run into the tens if not hundreds of millions of dollars. So, as for shell, (and maybe one or two others minor players) they have been around for a long time, in on the ground floor so to speak, so each new engine test is not an unsurmountable task.

I take it that you are into drag racing, and you probably well know that both synthetic, synthetic blend and petro-stock oils are used. The choice of the race team, or owner to the type of oil they use is probably either a recommendation of the engine builder, or even through brand loyalty. The reason why oxidation and varnish is not as apparent those engines is because of the fact that the oil is changed very frequently, especially depending on the class of car involved....as you know some of those high-dollar teams might only use an engine once, then change the engine..... Then completely tear down and rebuild the engine again!

Now, to get into the meat of your question..... You know there are several different types of "synthetic oils" on the market today. The most common that you will see as far as the "national brand" oils are actually either polyalphaolefins (pao), which are mostly blended with petro-stocks to produce a "semi-synthetic" or "synthetic blend" oil..... The trouble is the manufacturer does not need to say how much synthetic oil is in the blend...... Or oils made from group v base stocks, which is a process that has been developed in which petro-stocks are "re-worked" to have "synthetic-like characteristics." it is estimated that these oils are about $1.00 per gallon less to produce than the pao oils are, and they have pretty much taken over a large segment of the shares of the market. Did castrol, or the others lower the price of their oils when they went to this type of processing? - certainly not! They are allowed to call this oil a "synthetic" oil from a ruling by the ftc because of the fact that it has "synthetic-like properties." these engine oils are in a different category than what we in the industry call "true synthetic" oils such as red line and one or two versions of royal purple.....most other oils which call themselves "full synthetic" are using a legal loophole. (incidently, red line only makes synthetic oils, whereas royal purple makes both synthetic oil as well as "semi-synthetic" with a pao/petro-stock combination.) from what I understand, mobil 1 as well as amsoil are pao enhanced oils. Mobil at the present time is suffering from a pao shortage because of when hurricane ike went completely through their production facility in houston last year.

The reason I am relating all of the above is the fact that there are many different varieties and qualities of synthetic oils on the market, but the average consumer does not have any idea of how the whole marketing strategy has clouded the issue. There have been countless times when I have been talking up swepco's engine oils, and what we have been able to see them achieve, then the prospect will say: "sounds like a synthetic oil to me" and nothing could be further from the truth.

The biggest advantage of the pao and the newer so-called synthetic oil is the fact that they do have a lower pour point, and are really the best oils to use in arctic conditions. Some have a higher flash point to which you are alluding, the highest being the true synthetics such as red line produces. They do not use the same type of viscosity improvers due to the fact that the chemistry doesn't readily accept them. So, you are correct about what you call viscosity stabilizers, but only in certain oils.

For the most part, it has been acknowledged that mineral oils will handle 98% of the engine oil requirements for automotive (I lump in high performance in automotive), trucking and construction type equipment. The remaining 2% of the market has been overstated up to around 20 to 30% of consumer choice because of the marketing blitz favoring synthetic oils. It has even gone so far as that oem's have recommended synthetic oils for their cars to keep their warranty valid (which is not really necessary), for example, bmw for years has held the position that owners use their bmw 5w30 synthetic oil and change their oil every 15,000 miles to meet warranty requirements. They even come with free oil changes when you buy a new car and the dealership will not change the oil unless it has 15,000 miles on it..... Just ask an independent bmw shop what he thinks of that program after seeing all of the varnish and sludge in those engines!

Synthetic oils also need to have a robust additive package, but the problem with the paos is the fact that it does not hold the additives in suspension and they "drop out" and just lie there in the bottom of the oil pan. That is another reason why you do not see a lot of zinc in synthetic oils and the problem is that it is relying on the film strength of the oil to perform the necessary lubrication in the engines.

Yes turbo temperatures and ring temperatures can be a real killer on oil, but depending on the quality of the oil you choose, they are not necessarily deadly.

Swepco branded engine oils are not synthetic (can you tell by my diatribe?), they have been producing engine oil for over 75 years now and certainly have the ability to come up with a synthetic product. However, due to the fact that it would not be as good a product as our petro-stock engine oils are, they cannot see a reason to just be "another company who has a synthetic engine oil."

you sound as though you are pretty satisfied with the synthetic oil you have been using, and that is called "product loyalty," I've got a lot of customers who have switched and they are now loyal to swepco! My advice to you is that if you are totally happy with what you have and it has served you well, then stick with what you are doing, but if there is any kind of wonder in your mind that "maybe there is something better out there," then give us a try!

If your diesel pickup is pre 2007, make sure you use ci-4 rated oil in it as the new cj-4 has a much lower additive package. We make both the ci-4 as well as the cj-4 for newer engines and I've got customers who as an average change their oil every 15,000 miles....including those with light towing conditions. Price wise, we are going to be close with the "true synthetic" engine oils, quality wise, we are tops!

You asked, and that's my take on it.....I'm sure to draw some criticism, but that's the way it is! Some people really like synthetic oils and "swear by it" - I prefer to say that I "swear at it!"

keep up the good work,

dick
 
I want to thank you for a very thorough reply. I learned a lot.


I didn't realize all synthetics were not created equal. I have always used mobil 1 in my dd's. I see they are pao not the v modified versions so that is good. I have never used a blend or other brand for that matter.

I should go into my own testing and theory. Back when I chose to begin using 100% synth. Oils I did my own testing to determine coaking resistance. I placed 2 metal containers in my oven. 1 was a major brand mineral based oil the other was mobil 1. I subjected them to increasingly higher temperatures 1 hour each level, starting @ 300f by 25 degree increments and ending @ 500f. I had way to much time on my hands.:icon_eek:

the mineral based oil began to darken slightly at 300f and got worse until @ 500f it was dark brown. The residual was a varnished film by 400f.

Mobil 1 showed only a slight color change after the full test.

That did it for me knowing that 400f + is common for piston crown and upper ring temps during heavy duty operation. Turbo bearings on turbine side can exceed that unless allowed to cool at idle for 5 minutes.

I guess if one uses a good quality synthetic there are benefits. My oil changes are only 4000 miles apart because I am concerned more so by suspended and dissolved combustion by-products than oil degredation.

I am not quite sure I understand what you mean by "silver piston pins"?

Dick, again thank you for another great pice reading material.

Robert
 
Hey Robert.....

For whatever reason they have chosen, silver wrist pins in reciprocating aircraft engines as well as Locomotive engines seem to be the norm and both require special engine oils. Of course, this is a general statement, only based on my limited knowledge in those fields, but as far as I know accurate. It could be that some engines do not use silver wrist pins though as I have not stayed on top of that aspect of engine oils since we are not in that marketing area.

I'm glad I made some points with you on understanding synthetic oil, here's another one for you: you state that you use mobil 1 in your turbo diesel late model truck engine as well as in your passenger cars. Did you realize that there are different grades of mobil 1 oil, and that you should not be using a pcmo oil in your diesel truck engine? As far as I know, besides the mobil delvac 5w40, synthetic engine oil for h-d trucking, the only other mobil product which meets ci-4 and cj-4 is their mobil 1, 5w40 turbo diesel engine oil. If you are using any of the other mobil 1 product in your truck engine, the highest diesel rating they have is "cf" or "cd" which are very old specifications. They will not give the protection which is required of your "later model" diesel pickup.

Since I'm not sure of the year of your pickup, I have taken the liberty of researching some on the mobil 1, 5w40 turbo diesel engine oil against the swepco 303, 15w40 which is a post 2006 and the 306, 15w40 which is a pre 2007 product. Since the mobil is a lighter weight oil, it's pour point is just slighter lower than either of our oils....it is -39f wheras the 303 is -31f and the 306 is -27f. The flash point on the mobil is 435f whereas the swepco is 400 & 430 respectively. The swepco has a higher concentration of additives, which also include zddp, the main friction modifier. Note that the "other mobil 1 products" which are designated pcmos have a much lower zddp rating than the mobil 1 turbo diesel oil does......so, it is really important that if you are using any of the other formulations, to at least switch up to the one which is designed for your engine.

You must have had a lot of time on your hands to do the coking test you described...... You also must have a very understanding wife/so to stink up the kitchen like you did!

The point that I am trying to make here, is that as you acknowledged all motor oils (synthetic or petro-stock) are not created equal, it is your responsibility to use the correct engine oil for the application, otherwise you can find yourself in deep kim chee (if you've ever had it, you know how bad that can be!)

newer diesel engines have a ringland area higher up on the piston (closer to the crown) and do require oil which can handle the heat as well as prevent deposits on/around the rings and skirts. For this reason, consumers should be very careful about their choice of engine oil in diesel applications.

I've already plugged swepco's 303 & 306, so I'll leave it at that! As far as the assumption that there are deposits in the oil, the only real way to ascertain that is through the use of a used oil analysis. I have fleet customers who typically get 15,000 miles (change filter at 7,500 miles) and more out of the oil on trucks like yours, and that is with drivers that don't own the vehicle! (they are really tough on them) in h-d over the road trucking, believe it or not, but I have seen oil sample reports with the amazing results of over 200,000 miles, and cement mixers in excess of 2,500 hours using our products......but this cannot be done without using oil analysis, otherwise it's like playing russian roulette with your equipment.

Hope that helps!

Dick
 
Again thank you for putting time to inform us.

Sorry I was not more clear. I used mobil 1 in my gas dd's. I don't have a gas dd any longer so my truck is my dd now.
I assume the more obvious at times about the diesel/gas oil issue.:icon_neutral:

I do not Use mobil 1 in my diesel I use shell rotella t synthetic in it. Thanks for making sure all bases are covered.


You sparked a desire to truly understand the lack of zinc in av oils. I had issue with wrist pin composition not to doubt you but to further our understanding and because I consider every exchange of information as a potential to learn. I have majored many aviation engines due to tbo restrictions set forth by the manufacturer and due to substandard annual inspection out comes usually failing differential compression tests etc and have not come across any other wrist pin material except for steel. That doesn't by any means mean that some special instances don't exist just that I have not seen them.

After some reading in aviation related publications I found this little ditty on the avweb sight which I frequent as due diligence for my a&p license. This confirms a suspicion I have.

why shouldn't I use automotive oil in my airplane to take advantage of the more advanced technology?
while it is true that automotive oil is far more advanced than aviation oil, the answer lies in the fact that most aircraft engines are air-cooled while automotive engines are water-cooled. Air-cooled aircraft engines are built with greater clearances and are designed to consume (burn) some oil.

Water-cooled automotive engines are designed and built to much tighter tolerances, so they do not consume much oil. These differences in design tolerances are due to the large temperature differentials that are found in high-continuous-power-output, air-cooled, aircraft engines versus the low- and intermittent-power-output, water-cooled, auto engines.

There can be a 300 degree f temperature difference between the cylinder head and cylinder base in an operating aircraft engine. That kind of temperature differential causes a lot of distortion in the cylinder, necessitating the requirement for large clearances. Automotive engines, being water-cooled, have lower temperature differentials across the engine and thus suffer lower levels of distortion and can be designed and built to tighter tolerances.

Aircraft engines were designed before additives were available and have not really changed much over the years. When ashless dispersant oils were introduced for auto engines, they were also suitable for aircraft engines and eventually were adopted for aviation use.

However, when zinc antiwear and metallic detergents were formulated into auto oils, an important divergence occurred. Aircraft engines burn a fair amount of oil and, if these metal-containing detergents and antiwear compounds are present, they can form metallic ash deposits in the combustion chambers. These deposits can lead to destructive preignition, which could burn holes in the tops of pistons with obvious catastrophic results. For that reason, it was decided that aviation oils were to remain ashless to avoid the risk of metallic deposits.

The benefit of using ashless dispersant oils is, obviously, a cleaner engine. Aircraft engines would also benefit greatly from the addition of other automotive additives such as anti-wear, detergents, and corrosion inhibitors, but the downside is added cost. Ashless versions of these performance additives can cost up to 10 times more than standard ash-containing additives.
 
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Hey guys, did some checking around. The "silver" wrist pin mentioned is actually in the wrist pin bearing, not the pin itself. Radial engines have used them, don't know about inlines or opposed, and certain locomotive engines, primarily the diesels from GM's emd. Silver based bearing alloys, ag-pb, ag-cd; are very durable, high heat transfer, and a very low coefficient of friction. High end plain bearings as in rod & wrist pin, can come with a silver coating. Robert has probably seen that in performance catalogs.

I asked an "aviator",(long since retired because of health quals), at work about av oils. The main thing he said was that av engines run long times at steady throttle, so deposits follow a flow or burn pattern and can quickly build. Not like in automotive where power and throttle positions can constantly fluctuate.
 
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Robert,

thanks for the post, it looks like we both learned a little from each other on this issue. As I stated earlier, I have not really stayed on top of aviation oils as they are out of the market arena for our products, especially since we have a highly additized engine oil line. I'm thinking that the "silver wrist pin" information was somehow mistaken way back over 20 years ago, so even tho my long-ago memory seems to be better than my recent memory has been lately, it was probably wrong when I got it to start with! I do know that I am correct with the fact that diesel/electric engines in locomotives use silver wrist pins as we have made locomotive engine oil for special orders in the past...... Also I have a short-line railway company customer (does not buy engine oil), and the head mechanic and I have known each other for many years. He has told me horror stories about getting a batch of oil which was mis-labeled and ended up with major problems.

Most people don't realize that in a water cooled engine, approximately 40% of the cooling is done with oil, and 60% with the liquid coolant. Of course, the air-cooled engines like the earlier vws and the porsche's rely strictly on air and have special heads and liners. Our 306 does wonders in a porsche, and the factory recommended oil is mobil 1. With the advent of the new, lower additives in mobil 1, it has brought on many complaints of lifter clatter, and cam wear in the engines utilizing flat-tappet cams, so as a result, we have picked up a lot more business in the high-performance import market.

I'm glad that we got the diesel oil situation straight, and I guess that since you mentioned mobil 1, that was why I thought it was what you were using, not the rotella-t synthetic. Like I said, all oils are not alike, and I'd like the buyer to be aware.

Best regards,
dick
 
Greg, thanks for the bearing info. I know that radial engines have a very demanding master rod load profile that takes some special attention. In school we majored a r4360 as a extra project. Wow what a lot of work for two people. Never got to run it in the cell but it was fun as we ran out of time.:(

silver must give higher compressive load carring capability than babbit/lead but still have the benifits of the low friction coeficients of lead. Will dig into this further.

Dick thank's for being availible to learn us a thing or two. See.... We both have sumpin to learn.:gringrin:

Robert
 
Silver must give higher compressive load carring capability than babbit/lead but still have the benefits of the low friction coefficients of lead. Will dig into this further.
Robert

Ah babbitt bearings. I believe your correct silver increases the load carrying capability. I've poured bearings for heavy stationary machinery and we got some of their custom blended stuff to help with loads.

As for the oil, I just changed the oil in my Scout last night, I used swepco 15-40/306 oil was running 20-50/306. The lighter oil should help with the cooler temp. Should I have the oil tested?
There was not a lot of miles on it, but I did have a cooling issue over the summer and the motor was running a bit hotter then I like. That plus the cooler temp was the reason for the oil change and switch to a lighter wt oil. Jeff says he runs the 15-40 and changes it once a year, with about 5,000 miles of driving. I broke in my rebuilt engine with swepco and changed the oil after about 1,000 miles, (April time frame) I then drove it over the summer and just changed it again. I assume I'm getting a lot of blow by on a new engine and that too is reason for the oil change.
Now that the motor has a few more thousand miles on it I hope the oil will hold it's purple color longer.
 
Hi Craig,

good to hear from you again.

Regarding your concerns for changing the oil and testing, the 15w40 probably was a good choice, although the 20w50 would more than likely been fine too. I see that you go out in the snow from the pictures you posted, so in that case, a little lighter oil is probably best.

Unless you experienced sustained Temperatures of over 230 degrees f, I wouldn't really worry about the oil having broken down, but if you would like to test the oil you drained out, contact me with a pm and I will tell you what is involved. If you saved the oil you drained out, and it is in a clean container, without the oil filter being dumped in it, that is the only way you are going to get an accurate reading. The other problem with that is the fact that in order to get a representative sample of what is going on inside the engine, the oil should be drained while it is at operating temperature to hold the contaminants in suspension..... If it is in a drain pan at present, those contaminants will have fallen to the bottom. So, my take on it would be that if you wish to sample it, then wait until you have at least a couple thousand miles on the 15w40 you put in, and pull a sample through the dip-stick tube directly into a clean sample bottle (of course at operating temperature), otherwise you would be spending the cost of sampling and postage and not get a completely accurate report on the 20w50.

As with any lube product, the color is just a dye, and it is not unusual to see the purple color go away, it doesn't mean the oil is wearing out. In your almost-new engine, you should be all seated, ring wise, so you shouldn't be getting any blow by, is there an oil consumption problem that you know of?

Unless you continue to have overheating problems, a 5,000 mile drain interval would be my recommendation for either sampling or draining.

Thanks for using swepco products!

Dick
 
Well I won't be testing this oil:icon_neutral: of course I pour the oil filter oil into the drain pan. No temp's that high. As for oil consumption, it's not excessive, but it does take about a 1/2-1 qt on each trip out. Jeff said the rings in these engine are very hard and take a long time to seat. I know you don't approve, but the old finger test can back showing the oil was is good condition:winky:

anyway to remove varnish from the engine once its there?
 
Graig,
I have never had rings take longer than 500 miles to seal. I am talking about the hardest rings on the market in large displacment v8's and small 4 bangers. I assume you kept the oem valve stem oil managment system ( basicly none). I would be more appt to believe valve stems are the likely avenue for oil usage.

Although 1/2-1 quart per outing is a bunch. Was the outing going down a bunch of hills and how many miles?

Rk
 
I agree with Robert on the ring seating scenario, and also with the thought of the valve stem possibility. Are you getting any blue smoke when you start the engine cold? - that is a tip off to valve / oil consumption conditions.

With the "new" engine you have, I'm not sure why you are asking about varnish, so I am assuming it is for another vehicle you have. You should not be experiencing any kind of varnish problem with the Scout engine, especially using swepco 306 engine oil and with the little amount of miles you have on it.

The swepco 502 oil improver will help clean out engines with varnish and sludge. If there is a lot of it, we recommend a shortened drain interval after the first application as your filter might get plugged. Always use it with fresh oil for best results. The 502 is not neccessary to use with the swepco 306 engine oil. It is available from Jeff.

Dick
 
Yes lot of hills. I live at about 58 feet and we head into the mountains and run fire roads or hardcore trails. The puff of smoke at start up can be a lot, in fact I can just stop for a couple minutes and get a hugh cloud. Other times no cloud:sosp: just a puff. I was reading Jesse post on the valve guides, but looks like he had machine work done to fit some other parts. I don't want to pull the heads on a new motor. Was just hoping to find something that could be done with just the valve covers removed. I suspect the oil sitting in the valve cover near the rear and when a valve is open, allows oil to drain into the camber might be the cause?
 
yes lot of hills. I live at about 58 feet and we head into the mountains and run fire roads or hardcore trails. The puff of smoke at start up can be a lot, in fact I can just stop for a couple minutes and get a hugh cloud. Other times no cloud:sosp: just a puff. I was reading Jesse post on the valve guides, but looks like he had machine work done to fit some other parts. I don't want to pull the heads on a new motor. Was just hoping to find something that could be done with just the valve covers removed. I suspect the oil sitting in the valve cover near the rear and when a valve is open, allows oil to drain into the camber might be the cause?

The down hill sections will cause a lot of oil to be sucked by the intake guides. Also on the 9 stand rocker assemblies where 4 bolts penetrate the intake port can be another source of oil usage. The 4 bolts need a thread sealer to be applied or oil will be drawn by the threads and into the engine.

The standing oil at the rear of the head is well below the stems and not a likely source of your smoke. Assuming the drain back hole are clear.:icon_eek:

if you built the engine you will know what steps were taken during the build. Hope this helps.

Robert
 
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